Selection Criteria for Radionuclide of Interest in Neutron Activation Analysis
Abstract
This paper describes general selection criteria for suitable activation products to get maximum signal
to noise ratio in minimum time. The detection sensitivities for 71 elements which exist in nature, with
respect to neutron activation analysis, have been calculated and presented. The paper defines the
sensitivity as log (peak area/weight) produced for different radionuclides suitable for activation analysis
using five sets of experimental conditions. Although, the current sensitivity factors have been calculated
for miniature neutron source reactor (MNSR) having thermal neutron flux of 1012 cm-2 s-1; however, the
general pattern of elemental sensitivities will not be affected drastically by changing reactor type.
Normalized peak areas have also been presented for the identification of suitable activation products.
These normalized areas are independent of experimental conditions used and are therefore general in
nature. Finally, real data have been presented from our previous studies, which confirm present findings
and provide actual irradiation times along with useful gamma-rays used in the analysis.
References
IAEA, "Use of research reactors for neutron activation analysis, IAEA-TECDOC-1215", Vienna, (1998).
IAEA, "Applications of research reactors, Report No. NP-T-5.3", Vienna, (2014).
IAEA, "Practical aspects of operating a neutron activation analysis laboratory, IAEA-TECDOC-564", Vienna, (1990).
R.M. Lindstrom, "Nuclear analysis at NBS and NIST", J. Radioanal. Nucl. Chem., vol. 318, pp. 1465-1471, 2018.
R.R. Greenberg, P. Bode and E.A. De Nadai Fernandes, "Neutron activation analysis: A primary method of measurement", Spectrochimica Acta Part B: Atomic Spectroscopy, vol. 66, pp. 193-241, 2011.
G.M. Kolesov, N.A. Shubina and A.Y. Lyul, "Optimizing instrumental neutron activation analysis of extraterrestrial materials: Fragments of
lunar rocks, meteorites, chondrules, and ultrarefractory inclusions", J. Anal. Chem., vol. 56, pp. 1022-1028, 2001.
D.D. Burgess, "Optimization of neutron activation analysis by interactive computer graphics", J. Radioanal. Nucl. Chem., vol. 110, pp. 51-60, 2005.
M. Wasim, J.H. Zaidi, M. Arif and I. Fatima, "Development and implementation of k0-INAA standardization at PINSTECH", J. Radioanal. Nucl. Chem., vol. 277, pp. 525-529, 2008.
M. Wasim and J.H. Zaidi, "NUCDATA: a useful database for NAA lab", Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, vol. 481, pp. 760-764, 2002.
M. Wasim, W. Zafar, M. Tufail, M. Arif, M. Daud and A. Ahmad, "Elemental analysis of topaz from northern areas of Pakistan and assessment of induced radioactivity level after neutron irradiation for color induction", J. Radioanal. Nucl. Chem., vol. 287, pp. 821-826, 2011.
M. Wasim, M. Arif, J.H. Zaidi and Y. Anwar, "Development and implementation of k0-INAA standardization at 10 MW Pakistan research reactor-1", Radiochim. Acta, vol. 97, pp. 651-655, 2009.
M. Wasim, M. Arif, J.H. Zaidi and I. Fatima, "Quantitative analysis of ancient Chinese ceramic using k0-instrumental neutron activation analysis", Radiochim. Acta, vol. 96, pp. 863-866, 2008.
M. Wasim, M. Arif, S. Iqbal and M. Daud, "Provisional elemental values for IAEA-Sewage Sludge by instrumental neutron activation analysis", Geostand. Geoanalytical Res., vol. 37, pp. 87-93, 2013.
M. Asim, M. Wasim and B. Mohammad, "Development of methodologies for the analysis of uranium ores by k0-instrumental neutron activation analysis and inductively coupled plasma atomic emission spectrometry", J. Radioanal. Nucl. Chem., vol. 311, pp. 1963-1969, 2017.
M. Wasim, S. Iqbal and M. Ali, "Radiological and elemental analysis of soils from Hunza in Central Karakoram using gamma-ray spectrometry and k0-instrumental neutron activation analysis", J. Radioanal. Nucl. Chem., vol. 307, pp. 891-898, 2015.
M. Wasim, A. Rahman, J. Zaidi, S. Waheed and S. Ahmad, "Neutron activation analysis of IAEA proposed certified reference material IAEA-407 (North Sea Fish Homogenate)", J. Radioanal. Nucl. Chem., vol. 254, pp. 219-222, 2002.
M. Wasim, S. Rehman, M. Arif, I. Fatima and J.H. Zaidi, "Neutron activation analysis and atomic absorption spectrometry for the analysis
of fresh, pasteurized and powder milk", Radiochim. Acta, vol. 100, pp. 51-56, 2012.
M. Wasim, M. Daud, M. Arif, S. Iqbal and Y. Anwar, "Characterisation of some exotic fruits (Morus nigra, Morus alba, Salvadora persica and Carissa opaca) used as herbal medicines by neutron activation analysis and estimation of their nutritional value", J. Radioanal. Nucl. Chem., vol. 292, pp. 653-659, 2012.
M. Wasim, N. Khalid, A. Asif, M. Arif and J.H. Zaidi, "Elemental characterisation of strawberry grown in Islamabad by k0-instrumental neutron activation analysis and atomic absorption spectrophotometry and its dietary assessment", J. Radioanal. Nucl. Chem., vol. 292, pp. 1153-1159, 2012.
M. Wasim, S. Iqbal and S. Rahman, "Fruit of Morus nigra and Morus alba as environmental biomonitor: an elemental analysis by k0-instrumental neutron activation analysis", J. Radioanal. Nucl. Chem., vol. 310, pp. 777-784, 2016.
M. Wasim, M. Arif and M.S. Iqbal, "Determination of elements in different parts of goat brain using k0 instrumental neutron activation analysis", J. Radioanal. Nucl. Chem., vol. 300, pp. 249-254, 2014.
M. Wasim and S. Ahmad, "Comparison of two semi-absolute methods: k0 -instrumental neutron activation analysis and fundamental parameter method X-ray fluorescence spectrometry for Ni-based alloys", Radiochim. Acta, vol. 103, pp. 533–540, 2015.
N. Khalid, M. Wasim, N.A. Lodhi and M. Arif, "Performance evaluation of k0-instrumental neutron activation analysis and flame atomic absorption spectrophotometry in the characterization of various types of alloys", J. Radioanal. Nucl. Chem., vol. 297, pp. 153-159, 2013.