Local Polarization and Field Induced Anomaly in PLZT Relaxor Ferroelectric Ceramics
DOI:
https://doi.org/10.71330/thenucleus.2014.671Abstract
Lanthanum doped lead zirconate titanate (Pb1-xLax)(ZryTi1-y)O3 (PLZT x/y/1-y) relaxor ferroelectric ceramics show no macroscopic polarization down to low temperatures as shown by the present dielectric and Raman scattering measurements on PLZT-10/65/35. The measured inverse dielectric constant exhibited a broad minimum that was associated to the randomly oriented local polarization due to appearance of polar nanoregions (PNRs) below the Burns temperature (TB). The temperature dependence of such kind of local polarization was successfully calculated from the classical Landau theory of ferroelectric phase transitions. Electric field induced Brillouin scattering data also exhibited an abnormal shift at ï¾249 K that confirmed the switchable character of local polarization in relaxor ferroelectrics.References
G. H. Heartling and C. E. Land, J. Am. Ceram. Soc. 54 (1971) 1.
G. H. Heartling, Ferroelectrics 75 (1987) 25.
G. Shabbir and S. Kojima, J. Appl. Phys. 105 (2009) 034106.
J.-H. Ko, T. H. Kim, S. Kojima, X. Long, A. A. Bokov and Z.-G. Ye,
J. Appl. Phys. 107 (2010) 054108.
Z. Kutnjak, C. FilipÄc, R. Pirc, A. Levstik, R. Farhi and M.-El.
Marssi, Phys. Rev. B 59 (1999) 294.
G. Burns and F. H. Dacol, Phys. Rev. B 28 (1983) 2527.
D. Viehland Z. Xu and D. A. Payne, J. Appl. Phys. 74 (1993) 7454.
G. Shabbir, J.-H. Ko and S. Kojima, Appl. Phys. Lett. 86 (2005)
G. Shabbir, J.-H. Ko, S. Kojima and Q.-R. Yin, Appl. Phys. Lett. 82
(2003) 4696.
R. A. Cowley, Adv. Phys. 29 (1980) 1.
G. Shabbir and S. Kojima, EPL. 105 (2014) 57001.
Downloads
Published
How to Cite
Issue
Section
License
For all articles published in The Nucleus, copyright is retained by the authors. Articles are licensed under an open access licence [CC Attribution 4.0] meaning that anyone may download and read the paper for free. In addition, the article may be reused and quoted provided that the original published version is cited properly.